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title="技術(shù)交流" class=''>技術(shù)交流</a> </li> </ol> <div id="n4k4llnmk" class="met-shownews-content"> <section class="details-title border-bottom1"> <h1 class='m-t-10 m-b-5'>合成革霉變?cè)蚍治?/h1> <div id="n4k4llnmk" class="info font-weight-300"> <span>2015-09-21 11:59:43</span> <span>天緯化學(xué)</span> <span> <i class="icon wb-eye m-r-5" aria-hidden="true"></i> 317 </span> </div> </section> <section class="met-editor clearfix"> <p> 合成革霉變?cè)蚍治?/p> <p> 聚氨酯合成革在制成成品穿用時(shí)間不久，甚至在制作過(guò)程中（半個(gè)月之內(nèi)），革表面就出現(xiàn)微小裂紋，以致無(wú)法穿用而失去使用價(jià)值，究其原因，從合成革實(shí)際使用情況看，其生霉的最主要原因還是放置條件和使用方法不當(dāng)，如將合成革放在潮濕的有霉味庫(kù)房?jī)?nèi)，以及在加工使用合成革時(shí)，其背面往往貼襯布，有的還比較厚，短時(shí)間內(nèi)沒(méi)有完全干透，即進(jìn)入下一道工序，這種情況，十天半月之內(nèi)，合成革半成品和成品就會(huì)因長(zhǎng)霉而發(fā)生龜裂。<br /> 　　此外，聚氨酯合成革的主要成分是聚酰胺纖維和聚氨酯樹(shù)脂。聚酰胺纖維又稱(chēng)耐綸，是合成纖維，性質(zhì)比較穩(wěn)定，一般不受微生物的影響，而聚氨酯樹(shù)脂特別是聚酯型聚氨酯樹(shù)脂的防霉性能較差。<br /> 　　引起合成革霉變的外因是環(huán)境條件，即水分、濕度和微生物等，而內(nèi)因則是高分子材料的材質(zhì)成分，聚酯型聚氨酯是由聚酯與二異氰酸酯反應(yīng)，經(jīng)二元醇等擴(kuò)鏈劑擴(kuò)鏈生成聚氨酯，該種聚氨酯易水解。但即使在一定條件和溫度下處理后，聚氨酯材料仍可以保持其大部分耐折牢度。因此，短期內(nèi)發(fā)生龜裂不是聚氨酯濕熱水解的緣故，而是因?yàn)槲⑸锓置诿傅拇x產(chǎn)物損害了合成革表面，如微生物分泌的酯酶就可以催化酯類(lèi)水解。<br /> 　　聚氨酯合成革水解的另一個(gè)原因是在調(diào)配聚氨酯溶液時(shí)，加入包括了硬脂酸甲酯、纖維素粉、炭黑、鈦白粉等助劑，在生產(chǎn)工藝中，還加入脂肪酸類(lèi)油劑，這些添加劑也可以受到霉菌的侵害，為霉菌利用和分解，導(dǎo)致合成革表面出現(xiàn)損害。</p> <p> </p> <p style="padding-top: 26px; color: rgb(51, 51, 51); border: 0px; word-wrap: break-word; font-family: 微軟雅黑, 宋體; line-height: 26px; background-color: rgb(255, 255, 255);"> <span style="line-height: 28px; font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun;">我公司推出</span><a herf="http:///product/52-cn.html" href="http:///product/52-cn.html" style="text-decoration: none; font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; font-size: 12px; line-height: 1.5; text-align: center;" target="_blank" title="3Q-303 皮革防霉劑">3Q-303 皮革防霉劑</a><span style="font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; line-height: 2;">是廣譜</span><a class="seolabel" herf="http:///" href="http:///" style="font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; line-height: 2;" target="_blank" title="殺菌劑">殺菌劑</a><span style="font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; line-height: 2;">，它由幾種高效<a class="seolabel" herf="http:///" href="http:///" target="_blank" title="殺菌劑">殺菌劑</a>復(fù)配而成，可殺滅細(xì)菌、酵母菌和真菌。</span><span style="font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; line-height: 2;">在制革領(lǐng)域本品可作為鮮皮浸水時(shí)的<a class="seolabel" herf="http:///" href="http:///" target="_blank" title="殺菌劑">殺菌劑</a>或作為生皮浸酸時(shí)的<a class="seolabel" href="http:///" target="_blank" title="殺菌劑">殺菌劑</a>，同時(shí)也可作為皮化產(chǎn)品的罐內(nèi)</span><a class="seolabel" herf="http:///" href="http:///" style="font-family: 'Microsoft YaHei', Tahoma, Verdana, Simsun; line-height: 2;" target="_blank" title="防腐劑">防腐劑</a><span style="font-family: 'Microsoft YaHei', Tahoma, Verdana, 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